Amedeo Avogadro (1776-1856) in 1821 had proposed that since two volumes of hydrogen gas unite with one volume of oxygen gas, then water is composed of two atoms of hydrogen and one atom of oxygen. In a previous chapter, we described how John Dalton, the founder of atomic theory, stated that the formula of water was HO, and that consequently the respective atomic weights of hydrogen and oxygen were 1 and 8. Frequently the true atomic weight of an element was not certain, but instead could be a multiple or fraction of the apparent equivalent weight. Unfortunately, even though Berzelius had made very precise measurements, the valence of the elements was not well understood. These arithmetic comparisons depended upon the accurate atomic weights determined by Berzelius ( discussed in a previous chapter). For example, for the alkaline earths, the atomic weight of strontium (42.5) was the arithmetic mean of calcium (20) and barium (65). Johan Wolfgang Döbereiner (1780-1849) in 1829 of the University of Jena (the same university where Karl Marx studied) noticed that there were several “triads” of chemically similar elements in which the middle element had an atomic weight half-way between those of the other two elements. However, scientists are forever searching for fundamental order and patterns, and as additional elements were discovered, trends were observed. Lavoisier’s list was composed of a medley of “simple substances” (as he called them) which he organized into four categories: basic elements (gases), metals, nonmetals, and earths. Modern scientists have found smaller particles that make up the protons, neutrons, and electrons, although the atom remains the smallest unit of matter that can't be divided using chemical means.In 1789 Lavoisier turned the concept of “element” on its head when he proposed that water was a compound and that hydrogen, oxygen, carbon, sulfur, iron, copper, and 25 other substances were the true elements. For atoms with a high number of electrons, relativistic effects come into play, since the particles are moving at a fraction of the speed of light. Rather than the circular orbits of Rutherford's model, modern atomic theory describes orbitals that may be spherical, dumbbell-shaped, etc. The electron can potentially be found anywhere in the atom but is found with the greatest probability in an atomic orbital or energy level. Quantum mechanics led to an atomic theory in which atoms consist of smaller particles. This, in turn, led to Werner Heisenberg's uncertainty principle (1927), which states that it's not possible to simultaneously know both the position and momentum of an electron. Louis de Broglie proposed a wavelike behavior of moving particles, which Erwin Schrödinger described using Schrödinger's equation (1926). In 1913, Frederick Soddy described isotopes, which were forms of an atom of one element that contained different numbers of neutrons. Several discoveries expanded the understanding of atoms. The model and its validation in 1908 by Jean Perrin supported atomic theory and particle theory.īohr's model explained the spectral lines of hydrogen but didn't extend to the behavior of atoms with multiple electrons. In 1905, Albert Einstein postulated that Brownian motion was due to the movement of water molecules. Avogadro's law made it possible to accurately estimate the atomic masses of elements and made a clear distinction between atoms and molecules.Īnother significant contribution to atomic theory was made in 1827 by botanist Robert Brown, who noticed that dust particles floating in water seemed to move randomly for no known reason. In 1811, Amedeo Avogadro corrected a problem with Dalton's theory when he proposed that equal volumes of gases at equal temperature and pressure contain the same number of particles. His oral presentation (1803) and publication (1805) marked the beginning of the scientific atomic theory. He proposed that each chemical element consists of a single type of atom that could not be destroyed by any chemical means. Dalton's law of multiple proportions drew from experimental data. These theories didn't reference atoms, yet John Dalton built upon them to develop the law of multiple proportions, which states that the ratios of masses of elements in a compound are small whole numbers. Ten years later, Joseph Louis Proust proposed the law of definite proportions, which states that the masses of elements in a compound always occur in the same proportion. In 1789, Antoine Lavoisier formulated the law of conservation of mass, which states that the mass of the products of a reaction is the same as the mass of the reactants. It took until the end of the 18th century for science to provide concrete evidence of the existence of atoms.
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